赵蓓

工作经历

1995年苏州大学有机化学专业毕业，获硕士学位，期间赴南开大学做访问学者1年。同年留校工作，2006年获有机化学博士学位。

2011年获得江苏政府留学基金资助，赴新加坡访学。

科研成就

稀土金属有机化合物的合成、结构及其催化性质，导向有机合成的金属有机化学，不对称合成等。

主要贡献

主持国家自然科学基金2项，江苏省高校自然科学研究项目1项，参加2项国家自然科学基金项目和1项省部级项目。在国内外化学核心期刊如Green Chem., Org. Lett., Org. Chem. Front., Dalton Trans., Organometallics, Catal. Sci. Technol., J. Polym. Sci. Polym. Chem.等发表论文数十篇，授权发明专利4项。

主要论文：

1. Intermolecular addition of alcohols to carbodiimides catalyzed by rare-earth metal amides

L. J. Hu,C. R. Lu,

B. Zhao

*, Y. M. Yao

Org. Chem. Front.,

2018

, DOI: 10.1039/C7QO00991G

2. An amidato divalent ytterbium cluster: synthesis and molecular structure, its reactivity to carbodiimides and application in the guanylation reaction

C. Gong, H. Ding, C. R. Lu,

B. Zhao

*, Y. M. Yao

Dalton Trans.,

2017

,46, 6031-6038.

3.Efficient asymmetric hydrophosphonylation of unsaturated amides catalyzed by rare-earth metal amides [(MeSi)N]RE(m-Cl)Li(THF)with phenoxy-functionalized chiral prolinols

Z. H. Fei, C. Zeng, C. R. Lu,

B. Zhao

*, Y. M. Yao

RSC Adv.

2017

,7, 19306-19311.

4. Synthesis and characterization of bridged bis(amidato) rare earth metal amides and their applications in C–N bond formation reactions

B. Zhao

,* Y. Xiao, D. Yuan, C. R. Lu, Y. M. Yao

Dalton Trans.

2016

,45, 3880-3887.

5. Asymmetric michael addition of malonates to unsaturated ketones catalyzed by rare earth metal complexes bearing phenoxy functionalized chiral diphenylprolinolate ligands

Q. Q. Qian, W. G. Zhu, C. R. Lu,

B. Zhao

*, Y. M. Yao

Tetrahedron: Asy.

2016

,27, 911-917.

6.Synthesis and characterization of amidato divalent lanthanide complexes and their use in forming 2,4-quinazolidinones from COand 2-aminobenzonitriles

Q. Y.Wang,C. R.Lu,

B.Zhao*,

Y. M.Yao

Eur. J. Org. Chem.,

2016

, 2555-2559.

7. Carboxylation of terminal alkynes with COcatalyzed by bis(amidate) rare-earth metal amides

H. Cheng,

B. Zhao

,* Y. M. Yao, C. R. Lu

Green Chem.,

2015

,17, 1675-1682.

8.Highly enantioselective epoxidation ofα,β-unsaturated ketones catalyzed by rare-earth amides [(MeSi)N]RE(μ-Cl)Li(THF)with phenoxy-functionalized chiral prolinols

C. Zeng, D. Yuan,

B. Zhao

,* Y. M. Yao

Org. Lett.,

2015

,17, 2242-2245.

9. Synthesis and characterization of bis(amidate) rare-earth metal amides and their application in catalytic addition of amines to carbodiimides

H. Cheng, Y. Xiao, C. R. Lu,

B. Zhao

,* Y. R. Wang, Y. M. Yao

New J. Chem.,

2015

,39, 7667-7671.

10. Synthesis and characterization of rare-earth metal complexes supported by a new pentadentate Schiff base and their application in heteroselective polymerization of rac-lactide

Y. Cui, W. K. Gu, Y. R. Wang,*

B. Zhao

,* Y. M. Yao, Q. Shen

Catal. Sci. Technol.,

2015

,5, 3302-3312.

11.Synthesis and characterization of rare-earth metal guanidinates stabilized by amine-bridged bis(phenolate) ligands and their application in the controlled polymerization ofrac-lactide andrac-b-butyrolactone

T. H. Zeng, Q. Q. Qian,

B. Zhao

,* D. Yuan, Y. M. Yao*, Q. Shen

RSC Adv.

2015

,5, 53161-53171.

12.C-N bond formation reaction catalyzed by Organo-rare-earth metal amides (Invited Review)

Y. Xiao, Q. Y. Wang,

B. Zhao

*, Y. M. Yao*

Chin. J. Org. Chem.

2015

,35, 1598-1614.

13.Asymmetric epoxidation of unsaturated ketones catalyzed by heterobimetallic rare-earth-lithium complexes bearing phenoxy functionalized chiral diphenylprolinolate ligand

Q. Q. Qian, Y. F. Tan,

B. Zhao

,* T. Feng, Q. Shen, Y. M. Yao*

Org. Lett.,

2014

,16,4516-4519.

14.Synthesis and characterization of amidate rare-earth metal amides and their catalyticactivities toward hydrophosphonylation of aldehydes and unactivated ketones

L. Zhao, H. Ding,

B. Zhao

,* C. R. Lu, Y. M. Yao

Polyhedron,

2014

,83, 50-59.

15. Asymmetric hetero-Diels-Alder reaction of Danishefsky’s dienes witha-carbonyl esters catalyzed by an indium(III)-PyBox complex

B. Zhao

, T. P. Loh

Org. Lett.,

2013

,15, 2914-2917.

16.Unexpected C?H bond activation promoted by bimetallic lanthanide amido complexes bearing a META-phenylene bridged bis(β-diketiminate) ligand

S. Sun, Q. Sun,

B. Zhao

*, Y. Zhang, Q. Shen, Y. M. Yao*

Organometallics,

2013

,32, 1876-1881.

17.Bimetallic lanthanide amido complexes as highly active initiators for the ring-opening polymerization of lactides

S.Sun, K. Nie, Y. F. Tan,

B. Zhao

*, Y. Zhang, Q. Shen, Y. M. Yao*

Dalton Trans.,

2013

,42, 2870-2878.

18.Synthesis and structural diversity of lanthanide amidate complexes and their catalytic activities for the ring-opening polymerization ofrac-lactide

X.L. Hu, C. R. Lu, B. Wu, H. Ding,

B. Zhao

*, Y. M. Yao*, Q. Shen

J. Organomet. Chem.,

2013

,732, 92-101.

19.Addition of terminal alkynes to aromatic nitriles catalyzed by divalent lnathanide amides supported by amidates: synthesis of ynones

H. Ding, C. R. Lu, X. L. Hu,

B. Zhao

*, B. Wu, Y. M. Yao*

Synlett,

2013

,24, 1269-1274.

20.Ring-opening polymerization of trimethylenecarbonate by the bridged diphenoxo ytterbium (II) complex

B. Zhao

, X. L. Hu, C. R. Lu

J. Appl. Polym. Sci.,

2011

,120, 2693.

21.One-pot synthesis of salicylanilides by direct amide bond formation from salicyclic acid under microwave irradiation

C. R. Lu,

B. Zhao*

, Y. P. Jiang, H. Ding, S. Yang

Syn. Commun.,

2011

,41, 1257.

22.Ring-opening polymerization of trimethylenecarbonate and its copolymerization withe-caprolactone by lanthanide (II) aryloxide complexes

B. Zhao

, C. R. Lu, Q. Shen

J. Appl. Polym. Sci.,

2007

,106, 1383.

23. Metallomacrocycle complexes of lanthanides with bridged amide ligands: syntheses and molecular structures of [{μ-p-(MeSiN)CH}YbCl(THF)]and [{μ-p-(MeSiN)CH}Nd(μ-Cl)(THF)]·2PhMe

B. Zhao

, H. H. Li, Q. Shen, Y. Zhang, Y. M. Yao, C. R. Lu

Organometallics,

2006

,25, 1824.

24.Polymerization of N-phenyl maleimide by lanthanide complexes

B. Zhao

, Y. R. Wang, C. R. Lu, Q. Shen, M. Y. Deng

J.Polym. Sci. Polym. Chem.,

2005

,43, 3966.

时间奖项全称具体奖项2009年江苏省科学技术进步奖二等奖2010年中国石油和化学工业协会科学技术进步一等奖